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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/5569


    Title: 有機-無機電/磁混成電荷轉移錯化合物和固態氧化物離子導電材料
    Other Titles: Organic-Inorgaic Conducting/Magnetic Hybrid Charge-Transfer Complexes and Solid Oxide Ionic Conductors
    Authors: 高惠春;王啟銘
    Contributors: 淡江大學化學學系
    Date: 2004
    Issue Date: 2009-03-16 12:41:59 (UTC+8)
    Abstract: 本研究計畫第一部份的主要目的是將具有導電性之有機分子與無機磁 性陰離子合在一起,形成電荷轉移錯合物,使它們變成一種具備電性與磁 性的雙功能材料。其通式可寫成 [org]n[M(L)x]m,此處的org 為有機電子授 體 (electron donors),M 為過渡金屬或稀土金屬元素,L 為配位子。本計畫 將成長單晶或薄膜,並以X-光繞射解析分子構造、拉曼光譜、CV 氧化還 原、變溫導電度及變溫磁化率等物性與化性量測獲取這些電/磁雙功能材料 的特性。所使用之有機分子與無機磁性陰離子如下:磁性無機陰離子: [M(III)(C2O4)3]3–, M = Cr, Fe, Mn, Co, Nd, Er, Eu, Gd; [Ln(NO3)5]2–, Ln = Nd, Er, Eu, Gd; [M(III)(CN)6]3–, M = Fe, Cr; [M(III)X4]–, M = Fe, Co, Mn, X = Cl, Br; [M(II)X4]2–, M = Fe, Mn, X = Cl, Br 或M(NIT-CO2 –), [M = Ag(I) 或 Cu(I), NIT = nitronyl nitroxide radicals] 等。 本研究計畫第二部份的主要目的是改良現有之固態氧化物燃料電池中 的氧離子導體和鋰電池中的鋰離子導體,使其導電度增加,更適合於商業
    Appears in Collections:[化學學系暨研究所] 研究報告

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