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    題名: Sequential Electrochemical Oxidation of Alternating Benzene-Furan Oligomers
    作者: Lin,  C.-L. ;Wu, Y.-L.;Chen, C.-L.;Chou, C.-M.;Luh, T.-Y
    貢獻者: 淡江大學化學工程與材料工程學系
    日期: 2007-10-01
    上傳時間: 2011-05-20 09:54:20 (UTC+8)
    出版者: American Chemical Society
    摘要: Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.
    關聯: The Journal of Organic Chemistry 72(22), pp.8531-8534
    DOI: 10.1021/jo070999+
    顯示於類別:[化學工程與材料工程學系暨研究所] 期刊論文

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