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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/53660

    Title: Sequential Electrochemical Oxidation of Alternating Benzene-Furan Oligomers
    Authors: Lin,  C.-L. ;Wu, Y.-L.;Chen, C.-L.;Chou, C.-M.;Luh, T.-Y
    Contributors: 淡江大學化學工程與材料工程學系
    Date: 2007-10-01
    Issue Date: 2011-05-20 09:54:20 (UTC+8)
    Publisher: American Chemical Society
    Abstract: Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.
    Relation: The Journal of Organic Chemistry 72(22), pp.8531-8534
    DOI: 10.1021/jo070999+
    Appears in Collections:[Graduate Institute & Department of Chemical and Materials Engineering] Journal Article

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