銅(II)錯合物合成、構造、磁性及兒茶酚酶活性的研究

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Title:	銅(II)錯合物合成、構造、磁性及兒茶酚酶活性的研究
Other Titles:	Synthesis, structures, magnetic properties, and catecholase-like activities of Cu(II) complexes
Authors:	饒瑞峪;Rao, Ruei-yu
Contributors:	淡江大學化學學系碩士班魏和祥;Wei, Ho-hsiang
Keywords:	磁性;兒茶酚酶活性反應;Schiff base,copper(II) complexes;magnetic properties catecholase activity;X-ray structure
Date:	2010
Issue Date:	2010-09-23 16:10:52 (UTC+8)
Abstract:	本論文以Schiff base方式合成四種配位基L1~L4，以不同架橋基合成銅(II)錯合物，討論其化學結構、磁性行為與兒茶酚酶 (Catecholase) 催化活性之關係。內容分成二部分，第一部分是銅(II)錯合物之合成與磁性行為。第二部分是兒茶酚酶(Catecholase)催化活性之探討。四個錯合物(1)~(4)分別為: (1)[Cu2(L1)-(μ-O)]．3H2O (2)[(CuL2)3-(μ3-OH)](ClO4)2．H2O (3)[Cu(L3)(CTZ)]2 (4)[Cu2(L4)4(K)]．2H2O L1: 2-(2-Hydroxyphenyl)-1,3-bis[2-(2-aminoethyl)imidazolidin-2-yl)phenoxy)acetic acid]imidazolidine L2: (Z)-4-(2-(ethylamino)ethylamino)pent-3-en-2-one L3: 2-((E)-(2-(dimethylamino)ethylimino)methyl)phenol L4: 2-((E)-(2-(dimethylamino)ethylimino)methyl)-6-methoxyphenol 銅(II)錯合物其性質由X-ray單晶繞射儀、紅外線光譜、元素分析儀來了解銅與銅之間配位立體結構與磁性行為的關聯性，並在UV-Vis光譜來觀察其特定吸收，探討其化學結構和Cu-Cu之間距離對兒茶酚酶(Catecholase)催化活性的影響。 The present paper discussion binuclear copper(II) complexs containing chemical constitution, magnetic behavior and relations of The reactive activies of catecholase-like. The content divides into two parts. Part I: binuclear copper (II) complexs synthesis and the magnetic behavior. Part II: The reactive activies of catecholase-like. (1)[Cu2(L1)-(μ-O)]．3H2O (2)[(CuL2)3-(μ3-OH)](ClO4)2．H2O (3)[Cu(L3)(CTZ)]2 (4)[Cu2(L4)4(K)]．2H2O L1: 2-(2-Hydroxyphenyl)-1,3-bis[2-(2-aminoethyl)imidazolidin-2-yl)phenoxy)acetic acid]imidazolidine L2: (Z)-4-(2-(ethylamino)ethylamino)pent-3-en-2-one L3: 2-((E)-(2-(dimethylamino)ethylimino)methyl)phenol L4: 2-((E)-(2-(dimethylamino)ethylimino)methyl)-6-methoxyphenol copper (II) complexs thing its nature by the single-crystal X-ray diffraction , the infrared spectra, and the element analyzer to understand that between the Cu-Cu coordinate spatial structure and the magnetic behavior''s relatedness, and observes its specific absorption in the UV-Vis spectra, discusses between its chemical constitution and Cu-Cu is away from to the catecholase catalytic activity influence.
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