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    題名: XANES Spectroscopic Studies of the Phase Transition in Gd2Zr2O7
    作者: 李攸軒;陳錦明;李志甫;高惠春
    貢獻者: 淡江大學化學學系
    關鍵詞: XANES spectra;Structural phase transition;Pyrochlore;Crystal field splitting energy;Gd2Zr2O7.
    日期: 2010-06
    上傳時間: 2013-07-29 13:44:50 (UTC+8)
    出版者: 臺北市:中國化學學會
    摘要: The structuralphase transition fromfluorite to pyrochloreand thestrength of thecoordination bond of
    Zr-O in Gd2Zr2O7 were investigated by XANES spectra of both O and Zr K-edge. The energy difference
    of the O K-edge absorption spectra at 532 and 536 eV was assigned to the crystal field splitting energy of
    the 4d orbital (E4d, t2g and eg) of the Zr ion. Also, in the samples prepared at higher temperatures, the 536 eV peak moves slightly to higher energy, whereas the absorption energy of 532 eV peak does not shift. A
    correlation between E4d and the strength of interaction between Zr (4d) and O (2p) orbitals has been
    found. Furthermore, two Zr K-edge absorptions at 18020 and 18030 eV of Gd2Zr2O7
    have been observed; the splitting energy (E), peak intensity ratio (I18030/I18020),
    and FWHM of the first derivative of the absorption curve depend on the preparation temperatures.
    The effect of crystal symmetry and Zr-O bonding character on the XANES spectral profile was discussed.
    關聯: Journal of the Chinese Chemical Society=中國化學會會誌 56(3), pp.543-548
    DOI: 10.1002/jccs.200900080
    顯示於類別:[化學工程與材料工程學系暨研究所] 期刊論文


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