淡江大學機構典藏:Item 987654321/44450
English  |  正體中文  |  简体中文  |  全文笔数/总笔数 : 62830/95882 (66%)
造访人次 : 4036734      在线人数 : 603
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜寻范围 查询小技巧：
  • 您可在西文检索词汇前后加上"双引号"，以获取较精准的检索结果
  • 若欲以作者姓名搜寻，建议至进阶搜寻限定作者字段，可获得较完整数据
    •  进阶搜寻


    jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/44450


    题名: Effect of the temperature of polyurethane dissolution on the mechanism of wet-casting membrane formation
    作者: Cheng, Liao-ping;Huang, Yen-shih;Young, Tai-horng
    贡献者: 淡江大學化學工程與材料工程學系
    关键词: Polyurethane;Dissolution temperature;Particulate membranes
    日期: 2003-03-01
    上传时间: 2010-03-09 10:22:27 (UTC+8)
    出版者: Elsevier
    摘要: An analysis of data from scanning electron microscopy (SEM), gel permeation chromatography (GPC) and differential scanning calorimetry (DSC) for two series of polyurethane membranes is presented. Membranes were prepared by direct immersion of the casting solution of polyurethane, dissolved in dimethyl formamide at different temperatures, into either water or 1-octanol bath at 25 °C. Depending on the temperature of polyurethane dissolution, a gradual variety in the membrane structure was observed by SEM. As the temperature of polymer dissolution was increased, the membrane structure changed from dense to cellular or particulate morphologies. On the basis of the GPC and DSC results, polyurethane molecular weight decreased but the degree of microphase separation caused by clustering of some of the soft and hard segments into separate domains in the membrane increased with increasing the temperature of polymer dissolution. It is thus proposed that the change in membrane structure is due to the variation of molecular weight of polyurethane, which in turn can change polymer chain mobility during membrane formation. In addition, the extent of microphase separation was described and related to the particulate morphology when 1-octanol was used as the nonsolvent.
    關聯: European polymer journal 39(3), pp.601-607
    DOI: 10.1016/S0014-3057(02)00235-5
    显示于类别:[化學工程與材料工程學系暨研究所] 期刊論文

    文件中的档案:

    档案 大小格式浏览次数
    0KbUnknown297检视/开启

    在機構典藏中所有的数据项都受到原著作权保护.

    TAIR相关文章

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回馈