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https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/4422
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| Title: | Cyanation of the Seven-Membered Ring of Diethyl Azulene-1,3- dicarboxylate |
| Authors: | Tadayoshi Morita;Kazuo Sasaki;林稟彬;Lin, Bing-Bing;Lin, Yun-shan;林雲山 |
| Contributors: | 淡江大學化學學系 |
| Keywords: | Cyanation;Electrophilic Arene;Azulene;Addition Oxidation;Potassium Cyanide;氰化;親電性芳香烴;薁;加成氧化;氰化鉀 |
| Date: | 1995 |
| Issue Date: | 2013-07-29 13:46:37 (UTC+8) |
| Publisher: | 臺北市：中國化學學會 |
| Abstract: | Reaction of diethyl azulene-1,3-dicarboxylate with potassium cyanide in dimethoxyethane gave diethyl 4-cyano-, 6-cyano-, and 4,6-dicyanoazulene-1,3-dicarboxylates. This cyanation involved addition of a cyanide ion to the seven- membered ring of azulene to form a cyclopentadienide ion, followed by oxidation. |
| Relation: | Journal of the Chinese Chemical Society=中國化學會會誌 42(5), pp.861-864 |
| DOI: | 10.1002/jccs.199500115 |
| Appears in Collections: | [化學學系暨研究所] 期刊論文
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| 0009-4536_42(5)p861-864.pdf | 182Kb | Adobe PDF | 270 | View/Open |
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