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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/4422

    Title: Cyanation of the Seven-Membered Ring of Diethyl Azulene-1,3- dicarboxylate
    Authors: Tadayoshi Morita;Kazuo Sasaki;林稟彬;Lin, Bing-Bing;Lin, Yun-shan;林雲山
    Contributors: 淡江大學化學學系
    Keywords: Cyanation;Electrophilic Arene;Azulene;Addition Oxidation;Potassium Cyanide;氰化;親電性芳香烴;;加成氧化;氰化鉀
    Date: 1995-01
    Issue Date: 2013-07-29 13:46:37 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: Reaction of diethyl azulene-1,3-dicarboxylate with potassium cyanide in dimethoxyethane gave diethyl 4-cyano-, 6-cyano-, and 4,6-dicyanoazulene-1,3-dicarboxylates. This cyanation involved addition of a cyanide ion to the seven- membered ring of azulene to form a cyclopentadienide ion, followed by oxidation.
    Relation: Journal of the Chinese Chemical Society=中國化學會會誌 42(5), pp.861-864
    DOI: 10.1002/jccs.199500115
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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