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    題名: A Model for the Passivation of the Zinc Electrode in Alkaline Electrolyte
    作者: Prentice, Geoffrey;Chang, Yu-chi;Shan, Xuning
    貢獻者: 淡江大學化學工程與材料工程學系
    關鍵詞: electrochemistry;dissolving;passivation;zinc;electrolytes
    日期: 1991-04
    上傳時間: 2010-03-09 10:02:47 (UTC+8)
    出版者: Pennington: Electrochemical Society
    摘要: We have developed a model for the anodic dissolution and passivation of the zinc electrode in alkaline electrolyte. The model is based on postulated elementary reactions. Species on the electrode surface are assumed to follow Langmuir behavior. In previous work we proposed a model for the dissolution kinetics in the prepassive region. In the present investigation we have extended this model to include the passivation process. Using our model, we are able to simulate the general features of the current‐potential behavior. Effects of hydroxide concentration and mass transport rates on current‐potential curves are qualitatively predicted by the model.
    關聯: Journal of the electrochemical society 138(4), pp.890-894
    DOI: 10.1149/1.2085742
    顯示於類別:[化學工程與材料工程學系暨研究所] 期刊論文


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