淡江大學機構典藏:Item 987654321/44200
English  |  正體中文  |  简体中文  |  Items with full text/Total items : 62830/95882 (66%)
Visitors : 4036001      Online Users : 820
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
    •  Adv. Search
    Home ‧ Login ‧ Upload ‧ Help ‧ About ‧ Administer Goto mobile version


    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/44200


    Title: Monte Carlo simulation of diepoxides and monoepoxides cured with amines
    Authors: Cheng, kuo-chung;Don, trong-ming;Rwei, syang-peng;Li, yu-ching;Duann, yen-fang
    Contributors: 淡江大學化學工程與材料工程學系
    Keywords: Amines;Computer simulation;Curing;Gelation;Gels;Molecular weight;Molecular weight distribution;Monte Carlo methods;Reaction kinetics;Sols;Cycle rank;Diamine;Diepoxides;Gel fraction;Molar mass distribution;Monoepoxides;Epoxy resins
    Date: 2002-09
    Issue Date: 2013-06-13 11:29:10 (UTC+8)
    Publisher: Hoboken: John Wiley & Sons, Inc.
    Abstract: The diepoxide–monoepoxide–diamine curing systems are investigated with a Monte Carlo simulation. The dependence of the molecular weight distribution (MWD), gel fraction, and cycle rank of the polymers on the differences in the epoxy reactivities and the contents of the monoepoxide as a reactive diluent are discussed. Before gelation, the MWD of the curing systems with a lower content of the monoepoxide is broader than the MWD of the curing systems with a higher content, and it leads to a lower critical conversion. The gel fraction and cycle rank of the polymers decrease with an increasing amount of the diluent. Even fully cured, the system with a 0.6 epoxy molar fraction of the monoepoxide still has a large fraction of sol, about 49%. Although the various reactivities of the monoepoxide result in different ways of forming gels during curing, the final gel fractions are always near 100% as long as the epoxy molar fraction of the diluent is no more than 0.2. The profiles of the molecular weights of the polymers calculated by the model are in agreement with the experimental data. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1857–1868, 2002
    Relation: Journal of Polymer Science, Part B: Polymer Physics 40(17), pp.1857-1868
    DOI: 10.1002/polb.10248
    Appears in Collections:[Graduate Institute & Department of Chemical and Materials Engineering] Journal Article

    Files in This Item:

    File Description SizeFormat
    0887-6266_40(17)p1857-1868.pdf256KbAdobe PDF194View/Open
    0887-6266_40(17)p1857-1868.pdf256KbAdobe PDF1View/Open

    All items in 機構典藏 are protected by copyright, with all rights reserved.

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback