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    題名: Thermochemical behavior of metallic citrate precursors for the production of pure LaAlO3
    作者: 余宣賦;Yu, Hsuan-fu;Wang, Juy;Wang, Shuen-shian;Kuo, Yu-man
    貢獻者: 淡江大學化學工程與材料工程學系
    關鍵詞: A. Ceramics;B. Chemical synthesis;C. Infrared spectroscopy;C. X-ray diffraction;D. Phase transitions
    日期: 2009-01
    上傳時間: 2010-08-10 10:41:13 (UTC+8)
    出版者: Kidlington: Pergamon
    摘要: Pure LaAlO3 nanoparticles were synthesized, using a citrate-precursor technique. La(NO3)3, Al(NO3)3, and C3H4(OH)(COOH)3, in a molar ratio of 1:1:4.5, were dissolved in deionized water. The pH of the aqueous solution was adjusted using NH4OH. After drying, the citrate precursors were charred at 350 °C, followed by calcination at different temperatures. The thermochemical behavior of the charred citrate precursor to form LaAlO3 was investigated using X-ray diffractometry, infrared spectroscopy, thermogravimetric analysis, and differential thermal analysis. While the charred specimen obtained at pH=2 (without NH4OH addition) was composed of LaAl(OOCH2)3, the charred specimens obtained at pH>2 were composed of LaAlO3−x−y(CO3)x(OH)2y. All these metallic salts were decomposed at temperatures between 600 and 780 °C to form crystalline LaAlO3 but calcining the specimens in air at 800 °C were required to remove all residual chars to produce pure LaAlO3. At 900 °C, the citrate-derived particles obtained at pH>2 were composed of LaAlO3 crystallites with an average size of 30 nm.
    關聯: Journal of Physics and Chemistry of Solids 70(1), pp.218-223
    DOI: 10.1016/j.jpcs.2008.10.005
    顯示於類別:[化學工程與材料工程學系暨研究所] 期刊論文


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