| 題名: | Preparation of NiFe2O4 powder by spray pyrolysis of nitrate aerosols in NH3 |
| 作者: | Yu, Hsuan-fu;Gandalla, Ahmed M. |
| 貢獻者: | 淡江大學化學工程與材料工程學系 |
| 日期: | 1996-03 |
| 上傳時間: | 2010-03-09 09:59:30 (UTC+8) |
| 出版者: | New York: Cambridge University Press |
| 摘要: | To avoid the formation of hollow spheres during spray pyrolysis, NH3 was employed to change the mechanism of forming NiFe2O4 from aerosols, containing Ni(II) and Fe(III) nitrates in the required stoichiometric ratio. Nearly spherical, solid submicron NiFe2O4 particles with narrow size distribution were produced in one step using a dilute aqueous solution at pyrolysis temperatures as low as 823 K. However, higher pyrolysis temperatures (≥1023 K) reduced the oxides to metallic alloy of Ni and Fe due to dissociation of NH3. The forming steps and possible reaction mechanisms for aerosol droplets involved in the process were discussed. |
| 關聯: | Journal of materials research 11(3), pp.663-670 |
| DOI: | 10.1557/JMR.1996.0080 |
| 顯示於類別: | [化學工程與材料工程學系暨研究所] 期刊論文
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