淡江大學機構典藏:Item 987654321/42053
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    題名: Effect of Ionic Sizes on the Electrophoretic Mobility of a Particle with a Charge-Regulated Membrane in a General Electrolyte Solution
    作者: Huang, Shih-wei;Hsu, Jyh-ping;Kuo, Yung-chih;曾琇瑱;Tseng, Shio-jenn
    貢獻者: 淡江大學數學學系
    日期: 2002-02-28
    上傳時間: 2010-02-23 14:48:53 (UTC+8)
    出版者: American Chemical Society (ACS)
    摘要: The electrophoretic mobility of a planar particle covered by a charge-regulated membrane in a mixed (a:b) + (c:b) electrolyte solution, taking the effect of the sizes of charged species into account, is analyzed theoretically. The influences of the key parameters, which include the frictional coefficient of the membrane layer, pH, membrane thickness, ionic strength, valence of counterions, fixed charge density, fraction of multivalent counterions, dissociation equilibrium constant of the functional groups, and sizes of cations and anions, are discussed. We demonstrate the importance of the ionic steric effects by showing a substantial difference between the classic point-charge model and the present model.
    關聯: Journal of Physical Chemistry B 106(8), pp.2117-2122
    DOI: 10.1021/jp011644b
    顯示於類別:[數學學系暨研究所] 期刊論文

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