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    题名: Approximate expression for the critical coagulation concentration of a general electrolyte solution
    作者: Hsu, Jyh-ping;Lin, Sung-Hwa;曾琇瑱;Tseng, Shio-jenn
    贡献者: 淡江大學數學學系
    日期: 2004-04-08
    上传时间: 2010-01-28 07:19:57 (UTC+8)
    出版者: American Chemical Society (ACS)
    摘要: The critical coagulation concentration of a colloidal dispersion for the case of a general electrolyte solution is estimated under the conditions of constant surface potential. By combination of the Langmuir approximation and the Debye−Huckel approximation, explicit expressions for the electrical potential, the osmotic pressure, and the electrical energy are derived, and the results are used to estimate the critical coagulation concentration of ionic species. The influence of the valence of ionic species on this concentration is discussed. We show that the Schultz−Hardy rule is invalid, in general, and that the effect of co-ions can be too large to be ignored.
    關聯: Journal of Physical Chemistry B 108(14), pp.4495-4500
    DOI: 10.1021/jp038019m
    显示于类别:[數學學系暨研究所] 期刊論文

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