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    Title: 草醯胺及苯甲酸銅錯合物之合成及性質
    Other Titles: Synthesis and characterizations of copper complexes with oxamide and benzoate ligands
    Authors: 林珮君;Lin, Pei-chun
    Contributors: 淡江大學化學學系碩士班
    王文竹;Wang, Wen-jwu
    Keywords: 草醯胺;苯甲酸;銅錯合物;oxamide;benzoate;copper complexes
    Date: 2005
    Issue Date: 2010-01-11 02:40:04 (UTC+8)
    Abstract: 本篇文章主要探討草醯胺及苯甲酸配位銅錯合物之合成及性質,將(3,4-bis-alkyloxy-benzoic acid sodium salt),及 (4-alkyloxy-benzoic acid sodium salt) 取代(μ-N,N''-Bis(2-pyridiylethyl) oxamidato(2-)-N1,N2,O1,O2;N1'', N2'',O1'',O2'')(nitrate-o)dicopper(II), [Cu2PEO(NO3)2]上的硝酸根,得到 (μ-N,N''-Bis (2-pyridiyl ethyl) oxamidato (2-)-N1,N2, O1,O2;N1'',N2'',O1'',O2'') ( 3,4-bialkyloxy- benzoate-o) dicopper(II),[2-CnCu2PEO]、(μ-N,N''-Bis (2-pyridiyl ethyl) oxamidato (2-)-N1,N2, O1,O2;N1'',N2'',O1'',O2'') (4-alkyloxy- benzoate-o) dicopper(II) [1-CnCu2PEO]兩個系列化合物,使用相同的方法,合成出具有溴取代基的系列(μ-N,N’-bis ((6-bromopyridin-2-yl)methyl) oxamidato(2-)-N1,N2,O1,O2 ; N1’,N2’O1’,O2’) (3,4,5-tris-dodecyloxy-benzoate-O)dicopper (II),[3-CnCu2BrPMO]。
    使用紅外光譜、電子吸收光譜以及電子順磁共振光譜鑑定。 1-C8Cu2PEO、1-C12Cu2PEO、2-CnCu2PEO利用超導量子干涉磁性儀測量磁性,耦合常數在169cm-1左右,顯示具有強的反鐵磁性。
    Three series of copper(II) complexes with the following structure: (μ-N,N''-Bis (2-pyridiyl ethyl) oxamidato (2-)-N1,N2, O1,O2;N1'',N2'',O1'',O2'') ( 3,4-bialkyloxy- benzoate-o) dicopper(II),[2-CnCu2PEO], and (μ-N,N''-Bis (2-pyridiyl ethyl) oxamidato (2-)-N1,N2, O1,O2;N1'',N2'',O1'',O2'') (4-alkyloxy- benzoate-o) dicopper(II) [1-CnCu2PEO] , and bromo substitution of pyridine on ligand and its dicopper complex (μ-N,N’-bis ((6-bromopyridin-2-yl)methyl) oxamidato(2-)-N1,N2,O1,O2 ; N1’,N2’O1’,O2’) (3,4,5-tris- dodecyloxy-benzoate-O) dicopper (II) [3-CnCu2PEO] were obtained and characterized by UV-vis, IR, and EPR. The squid data of 1-C8Cu2PEO、1-C12Cu2PEO、2-CnCu2PEO calculated J = 169 cm-1 which implied the strong antiferromagnetism.
    Appears in Collections:[化學學系暨研究所] 學位論文

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