利用X-ray吸收譜研究銪元素摻雜於氧化鋅奈米線

淡江大學機構典藏 > 理學院 > 物理學系暨研究所 > 學位論文 > Item 987654321/32556

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/32556

题名:	利用X-ray吸收譜研究銪元素摻雜於氧化鋅奈米線
其它题名:	X-ray absorption spectroscopic studies of Eu-doped ZnO nanowires
作者:	黃偉倫;Huang, Wei-lun
贡献者:	淡江大學物理學系碩士班彭維鋒;Pong, Way-faung
关键词:	銪元素摻雜於氧化鋅;氧化鋅;銪;吸收譜;Eu-doped ZnO;ZnO;EU;X-ray absorption
日期:	2009
上传时间:	2010-01-11 02:21:00 (UTC+8)
摘要:	本論文主要以X光吸收光譜實驗研究銪元素摻雜於氧化鋅奈米線的電子與原子結構。實驗包含室溫時以法線夾角37°入射樣品之X光吸收近邊緣結構(X-ray absorption near edge structure，XANES)、延伸X光吸收精細結構(Extended x-ray absorption fine structure，EXAFS)及樣品橫切面的掃描式光電子顯微能譜(Scanning Photoemission Microscope, SPEM)。由O K-edge XANES的吸收峰減弱與變寬與對照Eu L3-edge XANES，可推論樣品O 2p與Eu 5d有鍵結產生。EXAFS結合非線性最小方陣模擬(Nonlinear least squares fitting)電腦程式FEFFIT分析，顯示Eu可能會取代Zn或者填入Zn的空缺(vacancy)，但並沒有改變ZnO 之Wurtzite結構。SPEM可看到，靠近費米面的地方有Eu 4f 的貢獻。摻雜Eu使得ZnO表面的缺陷增加，因而增強了Eu-doped ZnO nanowire 的光激螢光的發光效率。 X-ray absorption near-edge structure (XANES), extended x-ray absorption fine structure (EXAFS), and Scanning photoemission microscope (SPEM) measurements were used to observe the influence of Eu-doped zinc oxide (ZnO) nanowires and to understand the unoccupied as well as occupied states of electronic structure and locally fine structure. The O K-edge XANES spectrum showed a broad and lower intensity compared to the undoped sample, which is interpreted as a rehybridization of the O2p derived state with the Eu5d state. This process lowers the energy of O2p states and enhances its occupancy by electrons from europium. EXAFS have revealed that Eu3+ ions maybe replaced Zn2+ in the Zn site, or filled-in in the Zn-site vacancies, but did not change the Wurtzite structure of host materials. The process thereby increases defects in the surface resulting to the enhanced PL of the Eu-doped ZnO nanowires.
显示于类别:	[物理學系暨研究所] 學位論文

文件中的档案:

档案	大小	格式	浏览次数
	0Kb	Unknown	419	检视/开启

在機構典藏中所有的数据项都受到原著作权保护.

TAIR相关文章

数据加载中.....