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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/27996

    Title: Size dependence of the electronic structure of copper nanoclusters in SiC matrix
    Authors: Shin, Dong-woon;Dong, Chungli;Mattesini, M.;Augustsson, A.;Mao, S.;張經霖;Chang, C. L.;Persson, C.;Ahuja, R.;Nordgren, Joseph;Wang, shan X.;Guo, J. H.
    Contributors: 淡江大學物理學系
    Date: 2006-06-01
    Issue Date: 2009-12-31 10:57:41 (UTC+8)
    Publisher: Elsevier
    Abstract: We studied the size dependence of the electronic structure of nanocrystalline copper embedded in silicon carbide by means of soft X-ray absorption spectroscopy. Changes in the local electronic states of copper nanoclusters, including the shift in binding energy and the reduction of s–p–d hybridization, occurred. The experimental result was compared with the ab initio self-consistent, real-space, multiple-scattering calculation. The calculation was in good agreement with the trend found in our experimental results. We concluded that the reduction of d–d interaction and the concomitant changes in s–p–d hybridization in copper nanoclusters arise due to the surface effect.
    Relation: Chemical Physics Letters 422(4-6), pp.543-546
    DOI: 10.1016/j.cplett.2006.03.026
    Appears in Collections:[Graduate Institute & Department of Physics] Journal Article

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