Magnetic and electronic properties of CeCo2 studied by synchrotron radiation

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Title:	Magnetic and electronic properties of CeCo2 studied by synchrotron radiation
Authors:	Dong, C. L.;Chen, C. L.;Asokan, K.;Chen, Y. Y.;Chen, P. C.;Liu, Y. S.;Chen, J. L.;張經霖;Chang, C. L.;Lin, H. J.;Lee, J. F.;Guo, J.-H.
Contributors:	淡江大學物理學系
Date:	2007-12
Issue Date:	2013-07-09 15:11:19 (UTC+8)
Publisher:	Weinheim: Wiley - VCH Verlag GmbH & Co. KGaA
Abstract:	The magnetic and electronic properties of CeCo2 bulk and nanoparticles have been investigated using element-specific techniques, X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD). The results of Ce L3-edge XAS spectra shows a higher spectral weight of 4f1 configuration in nanoparticles with respect to the bulk, which indicates that the valence of Ce is decreased in nanoparticles. In addition, spectroscopic results from the XMCD at Co L2, 3-edges and Ce M4, 5-edges indicate that CeCo2 undergoes a nonmagnetic to magnetic transition with size reduction. The variations in electronic and magnetic properties of nanoparticles were attributed to the charge transfer related to the sample dimension.
Relation:	Physica Status Solidi. B: Basic Research 244(12), pp.4526-4529
DOI:	10.1002/pssb.200777310
Appears in Collections:	[Graduate Institute & Department of Physics] Journal Article

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