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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/27662


    Title: Polymerization of a confined π-system : Chemical synthesis of tetrahedral amorphous carbon nanoballs from graphitic carbon nanocapsules
    Authors: 彭維鋒;Pong, Way-faung;Chu, C. C.;Hwang, G. L.;Chiou, J. W.;林正嵐;Lin, C. L.;Tsai, C. Y.;Lin, H. M.;Chang, Y. C.;Chang, C. S.;Hsu, A. H.;Huang, W. L.;Guo, J. H.;Chen, P. H.;Luh, T. Y.
    Contributors: 淡江大學物理學系;淡江大學化學工程與材料工程學系
    Keywords: Amorphous materials;Carbon nanostructures;anostructures;Pyrolysis
    Date: 2005-11
    Issue Date: 2009-12-31 10:35:08 (UTC+8)
    Publisher: Wiley-Blackwell
    Abstract: Aziridination of graphitic carbon nanocapsules (CNCs) followed by pyrolysis at 700 °C at ambient pressure yields tetrahedral amorphous carbon nanoballs (CNBs, see Figure). Because of the pyramidal character of some of the double bonds in the derivatized CNCs, a radical chain mechanism is proposed to rationalize the transformation of C sp2 hybridization in the CNCs to C sp3 hybridization in the CNBs.
    Relation: Advanced Materials 17(22), pp.2707-2710
    DOI: 10.1002/adma.200500757
    Appears in Collections:[物理學系暨研究所] 期刊論文
    [化學工程與材料工程學系暨研究所] 期刊論文

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