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    題名: Effects of composition on low temperature sinterable Ba-Nd-Sm-Ti-O microwave dielectric materials
    作者: Cheng, Chung-chin;Hsieh, Tsung-eong;林諭男;Lin, I-nan
    貢獻者: 淡江大學物理學系
    關鍵詞: Fused glass;Glass/dielectric composite;LTCC materials;Sol–gel derived glass
    日期: 2004
    上傳時間: 2009-12-31 10:34:42 (UTC+8)
    出版者: Elsevier
    摘要: This work investigated the effects of MgO and ZnO additives on the microwave properties of BRT114=[(BaO·R2O3·4TiO2)·0.06(2Bi2O3·3TiO2)] materials. Incorporation of small amount of ZnO (≦1 wt.%) markedly lowered the temperature coefficient of resonant frequency (τf), to around τf ≒1 ppm/°C, slightly increased the density and dielectric constant (εr) of the materials, but degraded the Q×f factor . Doping 2.5 mol% of MgO, in addition to ZnO, further improved the τf -value for the BRT114 materials. The dielectric constant and the Q×f factor of the materials degrade pronouncedly when doped with too abundant ZnO. Microstructure and EDX analyses indicated that the main factor for degrading the microwave properties is the induction on formation of secondary phases. Moreover, sol–gel and fused Ba–B–Si glass reacted with BRT114 in quite a different way. Fused glass wets BRT114 materials more easily than the sol–gel derived glass, resulting in composite materials with higher density and larger dielectric constant. Precalcining the glass-dielectrics mixture, greatly improved the wetting ability of the glass and markedly increased the microwave properties of the glass/dielectric composite, i.e. LTCC materials.
    關聯: Journal of the European Ceramic Society 24(6), pp.1787-1790
    DOI: 10.1016/S0955-2219(03)00493-X
    顯示於類別:[物理學系暨研究所] 期刊論文

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