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    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/27511

    題名: Structure and properties of (La2-xSrx)MnO4 compounds
    作者: Wu, M. S.;高惠春;Kao, H. C. I.;Sheu, H. S.;Chiang, Y. P.;Horng, L.;Hsueh, R. F.;Young, S. L.;彭維鋒;Pong, W. F.;Huang, J. H.
    貢獻者: 淡江大學物理學系;淡江大學化學學系
    關鍵詞: (La2-xSrx)MnO4;magnetoresistance;K2NiF4 structure;Jahn-Teller effect;preparation
    (La2-xSrx)MnO4;magnetoresistance;K2NiF4 structure;Jahn Teller effect;preparation
    日期: 2005-01-30
    上傳時間: 2009-12-31 10:13:50 (UTC+8)
    出版者: World Scientific Publishing
    摘要: Polycrystalline single phase (La2-xSrx)MnO4 (1.10≤x≤1.40) samples were prepared by a citrate precursor method. They have tetragonal K2NiF4 structure with a space group of 14/mmm, increasing x, unit-cell a-axis increases and c-axis decreases, which is a result of decreasing of the Jahn-Teller effect due to the increase of the Mn(IV) ion. Spin glass state exists at low temperature and a hump observed from the susceptibility (χ) measurement is probably caused by the interactions of several magnetic phases. Among them, (La0.6Sr1.4)MnO4 has the largest magnetoresistance ratio ([ρ(H)-ρ(0)]/ρ(0)), which reaches to 78.4% at 48 K. It is not possible to obtain single phase materials with 0.60≤x≤1.00 in the heat treatment temperature range of 1000-1600°C. Impurities were easily observed under SEM and X-ray diffraction patterns. Increasing the heating period and decreasing the temperature, the amount of ABO3 perovskite phase increases. In order to extend the solubility range, of the SrO in the (La2-xSrx)MnO4, it probably needs a higher temperature (>1600°C) and a shorter heat treatment period (<1 h).
    關聯: International Journal of Modern Physics B 19(1-3), pp.541-548
    DOI: 10.1142/S0217979205029006
    顯示於類別:[物理學系暨研究所] 期刊論文
    [化學學系暨研究所] 期刊論文


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