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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25755


    Title: Lewis acid-promoted reduction of bis(triorganotin) oxides to hexaorganoditins
    Authors: 李世元;Lee, Adam Shih-yuan;Zhang, Sh-lien
    Contributors: 淡江大學化學學系
    Keywords: Hexaorganoditin;Bis(triorganotin) oxide;Lewis acid;Reduction
    Date: 1997-12-05
    Issue Date: 2009-12-01 09:14:32 (UTC+8)
    Publisher: 中國化學會
    Abstract: Hexalkylditin is prepared by a Lewis acid-promoted (MgCl2) reductive reaction of bis(trialkyltin) oxide using magnesium metal as reducing agent. Hexabutyl- and hexaphenylditin are synthesized with 95% and 80% yield separately and a radical mechanism is proposed for the reaction condition. Unsymmetric ditin, Bu3Sn-SnPh3, was first synthesized by this reductive method.
    Relation: 1997中國化學會年會,頁279
    Appears in Collections:[化學學系暨研究所] 會議論文

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