197Au-Moessbauer spectroscopic data are presented for some organogold compounds of the type of RAuPPh3 and their binuclear cation complexes: [R(AuPPh3)2]BF4 (R=aryl groups). Both the 197Au- and 57Fe-Moessbauer parameters of ferrocenyl complex [(C5H5)Fe(C5H4)(AuPPh3)2]BF4 manifest a typical Au(I) state and ferrocene like Fe(II) state, respectively.
關聯:
Proceedings of international conference on the applications of the mossbauer effect, Jaipur, India, pp.689
