Binuclear Complexes (2):Electron Paramagnetic Resonance Study of Binuclear Copper Complexes with α-Diimine Ligand

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題名:	Binuclear Complexes (2):Electron Paramagnetic Resonance Study of Binuclear Copper Complexes with α-Diimine Ligand
作者:	Wang, Wen-jwu
貢獻者:	淡江大學化學學系
關鍵詞:	Binuclear complex;Electron paramagnetic Resonance
日期:	1990-12
上傳時間:	2009-12-01 09:01:01 (UTC+8)
出版者:	中國化學會
摘要:	A series of biouclear copper (II) complexes containing a-diimine ligand has been synthesized and characterized by electron paramagnetic resonance spectroscopy. The copper complexes of the form [Cu(dien)D](ClO4)2 or [Cu2(dien)2L](CIO4)4, where dien is diethylenetriamine, L' is monodentate ligand and L is bridging ligand, were studied. The EPR spectra were recorded in solution and frozen glassy solution. In the frozen solution spectra, the values of G‖ are in the range of 2.10 to 2.20, and the g⊥ are in the range of 2.03 to 2.06. Furthesmore, the values of A‖ are in the range of 170 to 188 gauss, and the A ⊥ are in the range of 17 to 32 gauss. The data indicate that the structure of Cu(II) complexes is axial symmetry in square pyramidal form.
關聯:	中國化學會會誌 37(6)，頁541-545
DOI:	10.1002/jccs.199000074
顯示於類別:	[化學學系暨研究所] 期刊論文

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