A two-dimensional CuIIGdIII compound self-assembled by H-bonding and intermolecular weak coordinate bonding between the dinuclear cores: structure and magnetic properties

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25456

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题名:	A two-dimensional CuIIGdIII compound self-assembled by H-bonding and intermolecular weak coordinate bonding between the dinuclear cores: structure and magnetic properties
作者:	魏和祥;Wei, Ho-hsiang;Mohanta, Sasankasekhar;Lin, Hsin-huang;Lee, Chin-jhan
贡献者:	淡江大學化學學系
关键词:	Two-dimensional;H-bonding;Magnetic properties;Gadolinium
日期:	2002-08-01
上传时间:	2009-12-01
出版者:	Elsevier
摘要:	A heteronuclear CuIIGdIII complex [CuIILGdIII(NO3)3] with the hexadentate Shiff-base compartmental ligand N,N′-ethylenebis(3-ethoxysalicylaldiimine) (H2L) has been synthesized and structurally characterized. The intermolecular semicoordination of nitrate oxygen to copper(II) results a one-dimensional zigzag chain, which are linked by H-bonding to form a two-dimensional sheet. Magnetic studies reveal ferromagnetic interaction within the dinuclear core and antiferromagnetic interaction propagated through the extended network (Full-size image (<1 K), where H=−2JSCu·SGd+β(gCu·SCu+gGd·SGd)H−zJ′〈S4Z〉S4Z).
關聯:	Inorganic Chemistry Communications 5(8), pp.585-588
DOI:	10.1016/S1387-7003(02)00482-3
显示于类别:	[化學學系暨研究所] 期刊論文

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