淡江大學機構典藏:Item 987654321/25429
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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25429


    Title: X-ray crystal structure of bis[1, 2-bis(dimethylphosphino) ethane]-dicarbonyltrifluorophosphinetitanium, a phosphine-substituted derivative of titanium heptacarbonyl
    Authors: Wreford, Stan S.;Fischer, Mark B.;Lee, Jung-Si;James, E. Joyce;Nyburg, Stanley C.
    Contributors: 淡江大學化學學系
    Date: 1981-01-01
    Issue Date: 2009-12-01
    Publisher: Cambridge: Royal Society of Chemistry (RSC)
    Abstract: Carbonylation of Ti(η-C4H6)2(dmpe)[dmpe = 1,2-bis(dimethylphosphino)ethane] or reduction of TiCl4.2THF in the presence of dmpe and CO affords [Ti(CO)3(dmpe)3/2]n which reacts wih PF3 and dmpe to form Ti(CO)2(PF3)(dmpe)2, [a derivative of the non-existent Ti(CO)7], the X-ray crystal structure of which is reported.
    Relation: Journal of the chemical society : chemical communications 10, pp.458-459
    DOI: 10.1039/C39810000458
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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