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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25417


    Title: Two New 3D Networks Co(II) Complexes Constructed via The Bridging Dicyanamide and 2,2’-Bipyrimidine Ligands : Structures and Magnetic Properties
    Authors: 陳志旺;魏和祥;Wei, Ho-hsiang;李綺縑
    Contributors: 淡江大學化學學系
    Keywords: Cobalt(II) complexes;Dicyanamide/2,2'-bipyrimidine bridges;X-ray crystal structure;3-D networks;Magnetic properties
    Date: 2006-12-01
    Issue Date: 2013-07-29 13:43:04 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: Two new complexes [Co(bipym)(dca)](dca) (1) and [Co(bipym)(dca)]2(ClO4)2 (CH3OH)×2H2O (2) (dca = dicyanamide, bipym = 2,2'-bipyrimidine) have been synthesized and their structuresl magnetically characterized. Complex 1 crystallizes in a monoclinic system P21/n space group, Z = 4, with a = 9.3710(2), b = 15.0690(3), c = 9.8920(2) A, β = 92.4780(10)°. Complex 2 crystallizes in a monoclinic system C2/c space group, Z = 4, with a = 16.4190(3), b = 17.0880(3), c = 12.1130(2) A, and β = 95.1070 (10)°. The crystal structure in 1 and 2 is a three-dimensional network contraction through the bridging 1,5-dca and bipym ligands. Temperature dependence of magnetic measurements show antiferromagnetic couplings in all cases with J = -7.22 for 1, and -7.11 cm-1 for 2, respectively.
    Relation: Journal of the Chinese Chemical Society=中國化學會會誌 53(6), pp.1291-1296
    DOI: 10.1002/jccs.200600172
    Appears in Collections:[化學學系暨研究所] 期刊論文

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