Triruthenium cluster complexes of C60 and C70 : Carbonyl site exchange probed via triphenylphosphine ligand derivatives

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25415

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题名:	Triruthenium cluster complexes of C60 and C70 : Carbonyl site exchange probed via triphenylphosphine ligand derivatives
作者:	徐秀福;Hsu, Hsiu-Fu;Shapley, John R.
贡献者:	淡江大學化學學系
关键词:	Fullerene complexes;Carbon-60;Carbon-70;Ruthenium;Cluster;Dynamic NMR
日期:	2000-04-09
上传时间:	2009-12-01
出版者:	Elsevier
摘要:	Carbon NMR data obtained for the fullerene complexes Ru3(CO)9(μ3-η2, η2, η2-C60) (1) and Ru3(CO)9(μ3-η2, η2, η2-C70) (2) suggest the operation of fluxional processes. Triphenylphosphine-substituted derivatives of 1 and 2 have been prepared by heating the fullerene complex with PPh3 in chlorobenzene at 130°C for a brief period. The individual mono- and disubstituted derivatives have been purified by thin-layer chromatography and identified by their infrared and FAB mass spectra, and their dynamic behavior has been probed by 31P- and 13C-NMR spectroscopy. Restricted three-fold rotations at each metal center are indicated for these derivatives.
關聯:	Journal of organometallic chemistry 599(1), pp.97-105
DOI:	10.1016/S0022-328X(00)00016-4
显示于类别:	[化學學系暨研究所] 期刊論文

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