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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25415


    Title: Triruthenium cluster complexes of C60 and C70 : Carbonyl site exchange probed via triphenylphosphine ligand derivatives
    Authors: 徐秀福;Hsu, Hsiu-Fu;Shapley, John R.
    Contributors: 淡江大學化學學系
    Keywords: Fullerene complexes;Carbon-60;Carbon-70;Ruthenium;Cluster;Dynamic NMR
    Date: 2000-04-09
    Issue Date: 2009-12-01
    Publisher: Elsevier
    Abstract: Carbon NMR data obtained for the fullerene complexes Ru3(CO)9(μ3-η2, η2, η2-C60) (1) and Ru3(CO)9(μ3-η2, η2, η2-C70) (2) suggest the operation of fluxional processes. Triphenylphosphine-substituted derivatives of 1 and 2 have been prepared by heating the fullerene complex with PPh3 in chlorobenzene at 130°C for a brief period. The individual mono- and disubstituted derivatives have been purified by thin-layer chromatography and identified by their infrared and FAB mass spectra, and their dynamic behavior has been probed by 31P- and 13C-NMR spectroscopy. Restricted three-fold rotations at each metal center are indicated for these derivatives.
    Relation: Journal of organometallic chemistry 599(1), pp.97-105
    DOI: 10.1016/S0022-328X(00)00016-4
    Appears in Collections:[化學學系暨研究所] 期刊論文

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