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    Title: A simple and highly efficient deprotecting method for methoxymethyl and methoxyethoxymethyl ethers and methoxyethoxymethyl esters
    Authors: 李世元;Lee, Adam Shih-yuan;Hu, Y. J.;Chu, S. F.
    Contributors: 淡江大學化學學系
    Keywords: MEM-esters;MOM-ethers;deprotection
    Date: 2001-03-10
    Issue Date: 2009-12-01
    Publisher: Elsevier
    Abstract: A series of methoxyethoxymethyl (MEM)- and methoxymethyl (MOM)-ethers and MEM-esters were hydrolyzed to their corresponding alcohols and carboxylic acids by a catalytic amount of CBr4 (10%) in iPrOH under refluxing reaction condition. The chemoselective hydrolysis between R3Si- and MEM-protected alcohols can be achieved by using different steric bulkness solvents such as MeOH or iPrOH.
    Relation: Tetrahedron 57(11), pp.2121-2126
    DOI: 10.1016/S0040-4020(01)00062-X
    Appears in Collections:[化學學系暨研究所] 期刊論文

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