淡江大學機構典藏:Item 987654321/25365
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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25365


    Title: The Polarographic Studies of Substituent Effects in Pyridine Complexes of Transition Metals
    Authors: 魏和祥;Wei, Ho-hsiang;Tsai, C. W.
    Contributors: 淡江大學化學學系
    Date: 1975-12-01
    Issue Date: 2013-07-29 13:46:45 (UTC+8)
    Publisher: 臺北市：中國化學學會
    Abstract: Polarographic reduction half=wave potentials for the series of inorganic complexes M(RC5H4N)2Cl2 (M=Co(II), Ni(II)m Cu(II), Zn(II), Cd(II); R=H, CH3, NH2, OH, CONH2, CHO, COCH3, COPh, Cl, Br and CH2OH) are reported to show the substituent effects in these complexes. consequently, the E1/2 values correlated linearly with Hammett substituent parameters, the slope of the E1/2 vs σ plots evidently decreases in order of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II).
    Relation: 中國化學會會誌=Journal of the Chinese Chemical Society 22(4)，頁285-290
    DOI: 10.1002/jccs.197500038
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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