淡江大學機構典藏:Item 987654321/25329
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    題名: Synthetic conductive materials (VI) synthesis and characterization of 3, 6-bis(2'-pyridyl)-pyridazine oxidation with iodine
    作者: 王文竹;Wang, Wen-jwu;Peng, S. M.
    貢獻者: 淡江大學化學學系
    日期: 1989-03-07
    上傳時間: 2009-12-01
    出版者: Elsevier
    摘要: The title compound was synthesized by mixing of 2,6-bis(2′-pyridyl)-pyridazine (PPA) with 20-fold iodine in acetonitrile. The black needle crystals were obtained after one month. The structure of this compound have been determined by single-crystal X-ray diffractometry. This crystal have P21/c space group with a = 7.620(3), b = 9.273(2), c = 25.006(6), ß = 98.70(3). The iodine is present as linear I3− form interrupted between stacking PPA column. Other physical properties characterized by elemental analysis, NMR, ESR, Raman, IR, UV/VIS/NIR, MS, magnetic susceptibility and electric conductivity will be discussed. The electric conductivity is 5×10−8 Scm−1 at room temperature and thermally activated with activation energy of 0.60eV.
    關聯: Synthetic metals 29(1), pp.531-535
    DOI: 10.1016/0379-6779(89)90345-7
    顯示於類別:[化學學系暨研究所] 期刊論文

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