English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 49350/84014 (59%)
造訪人次 : 7257013      線上人數 : 55
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25317

    題名: Synthesis, crystal structure, electrical properties, and band electronic structure of bis(1,3-propanediyldithio)tetrathiafulvalenium tetraiodoindate(III), (BPDT-TTF)3(InI4)2
    作者: 高惠春;Kao, Huey Chuen I.;Geiser, Urs;Wang, Hau H.;Schlueter, John;Chen, Marilyn Y.;Kini, Aravinda M.;Williams, Jack M.;Whangbo,Myung Hwan;Evain, Michel
    貢獻者: 淡江大學化學學系
    日期: 1988-11
    上傳時間: 2009-12-01
    出版者: American Chemical Society (ACS)
    摘要: A 3:2 salt (BPDT-TTF)â(InIâ)â was obtained by electrocrystallization and its structure was determined by single-crystal x-ray diffraction (triclinic, space group /bar P/1, a = 7.403 (2) /angstrom/, b = 9.170 (2) /angstrom/, c = 25.883 (7) /angstrom/, /alpha/ = 89.29 (2)/degree/, /beta/ = 96.34 (2)/degree/, /gamma/ = 92.83 (2)/degree/, V = 1774.2 (8) /angstrom/³, Z = 1). Analysis of the C/double bond/C and C/emdash/S bond lengths in the PT (i.e., BPDT-TTF) molecules suggest that this salt consists of donor molecules PT in two different oxidation states (i.e., BPDT-TTF/sup +/ and BPDT-TTF/sup 0.5+/). This oxidation assignment is consistent with the authors ESR measurements and band electronic structure calculations. The (BPDT-TTF)â(InIâ)â salt is a semiconductor at room temperature and below, which can be rationalized in terms of electron localization in the stacks of BPDT-TTF/sup +/ cations and the electronic instability associated with the well-nested Fermi surface for the layers of (BPDT-TTF)â/sup +/ dimers. Preliminary x-ray diffraction experiments indicate that (BPDT-TTF)â(T1Iâ)â is isostructural with (BPDT-TTF)â(InIâ)â. 28 refs., 7 figs., 3 tabs.
    關聯: Inorganic chemistry 27(23), pp.4284-4289
    DOI: 10.1021/ic00296a041
    顯示於類別:[化學學系暨研究所] 期刊論文


    檔案 描述 大小格式瀏覽次數



    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回饋