Synthesis, Crystal Structure and Magnetic Properties of Zinc(Ⅱ) Chloride Complexes with Pyridyl-substituted Nitronyl Nitroxides

doi:10.1002/jccs.200100102

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25313

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題名:	Synthesis, Crystal Structure and Magnetic Properties of Zinc(Ⅱ) Chloride Complexes with Pyridyl-substituted Nitronyl Nitroxides
作者:	李綺縑;魏和祥;李錦祥;王瑜
貢獻者:	淡江大學化學學系
關鍵詞:	Molecular magnetism;Crystal structure;Organic radicals;Nitronyl nitroxides;Magnetic properties
日期:	2001-08-01
上傳時間:	2013-07-29 13:40:11 (UTC+8)
出版者:	臺北市：中國化學學會
摘要:	aDeh-Yu College of Nursing and Management, Keelung, Taiwan 203, R.O.C. bDepartment of Chemistry, Tamkang University, Tamsui, Taiwan 251, R.O.C. cInstrument Center, College of Science, National Taiwan University, Taipei, Taiwan, R.O.C. ZnCl2(NIT-pPy) 1, (NIT-pPy = 2-(4-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl-3-oxide) crystallizes in the orthorhombic space group Pnn2 with the cell parameters a = 9.4083(9), b = 39.686(3), c = 7.4417(14) A. ZnCl2(NIT-6M-oPy) 2, (NIT-6M-oPy = 2-(6-methyl-2-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl-3-oxide) crystallizes in the monoclinic space group Pn with a = 7.377(2), b = 19.096(4), c = 11.853(2) A, b = 95.65(3)°. The temperature dependence magnetic susceptibility of complex 1 revealed an intermolecular ferromagnetic exchange interaction. A simple spin-polarization model has been used to justify the observed ferromagnetic exchange interaction between the spins of the radical NO group in complex 2.
關聯:	Journal of the Chinese Chemical Society=中國化學會會誌 48(4), pp.717-722
DOI:	10.1002/jccs.200100102
顯示於類別:	[化學學系暨研究所] 期刊論文

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