English  |  正體中文  |  简体中文  |  Items with full text/Total items : 58074/91663 (63%)
Visitors : 13730812      Online Users : 118
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25313

    Title: Synthesis, Crystal Structure and Magnetic Properties of Zinc(Ⅱ) Chloride Complexes with Pyridyl-substituted Nitronyl Nitroxides
    Authors: 李綺縑;魏和祥;李錦祥;王瑜
    Contributors: 淡江大學化學學系
    Keywords: Molecular magnetism;Crystal structure;Organic radicals;Nitronyl nitroxides;Magnetic properties
    Date: 2001-08-01
    Issue Date: 2013-07-29 13:40:11 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: aDeh-Yu College of Nursing and Management, Keelung, Taiwan 203, R.O.C. bDepartment of Chemistry, Tamkang University, Tamsui, Taiwan 251, R.O.C. cInstrument Center, College of Science, National Taiwan University, Taipei, Taiwan, R.O.C. ZnCl2(NIT-pPy) 1, (NIT-pPy = 2-(4-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl-3-oxide) crystallizes in the orthorhombic space group Pnn2 with the cell parameters a = 9.4083(9), b = 39.686(3), c = 7.4417(14) A. ZnCl2(NIT-6M-oPy) 2, (NIT-6M-oPy = 2-(6-methyl-2-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl-3-oxide) crystallizes in the monoclinic space group Pn with a = 7.377(2), b = 19.096(4), c = 11.853(2) A, b = 95.65(3)°. The temperature dependence magnetic susceptibility of complex 1 revealed an intermolecular ferromagnetic exchange interaction. A simple spin-polarization model has been used to justify the observed ferromagnetic exchange interaction between the spins of the radical NO group in complex 2.
    Relation: Journal of the Chinese Chemical Society=中國化學會會誌 48(4), pp.717-722
    DOI: 10.1002/jccs.200100102
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

    Files in This Item:

    File SizeFormat

    All items in 機構典藏 are protected by copyright, with all rights reserved.

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback