English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 49103/83224 (59%)
造訪人次 : 7028684      線上人數 : 56
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25311


    題名: Synthesis, crystal structure and magnetic properties of bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato) manganese(II) complexes with diazine ligands
    作者: Hong, D. M.;魏和祥;Wei, Ho-hsiang;Chang, K. H.;Lee, G. H.;Wang, Yu
    貢獻者: 淡江大學化學學系
    關鍵詞: crystal structure;magnetic properties;manganese complexes;binuclear complexes;diazine complexes
    日期: 1998-09-30
    上傳時間: 2009-12-01
    出版者: Elsevier
    摘要: One dinuclear [Mn2(hfac)4(μ-pyz)(H2O)2]2H2O (1) and three mononuclear complexes [Mn(hfac)2 (pym)(H2O)] (2), [Mn(hfac)2(pydz)2] (3), and [Mn(hfac)2(mpydz)2] (4) (Hhfac=1,1,1,5,5,5-hexafluoropentane-2,4-dione, pyz=pyrazine, pym=pyrimidine, pydz=pyridazine, and mpydz=3-methylpyridazine) have been synthesized and their crystal structures and cryomagnetic properties have been investigated. Complex 1 has a centrosymmetric dinuclear structure with two adjacent manganese atoms linked by a pyz ligand. The geometry about each manganese atom is distorted octahedral with NO5 coordination sphere. The structure of complex 2 is a mononuclear manganese complex with a distorted octahedral geometry of NO5 coordination sphere. The crystal structures of complexes 3 and 4 consist of mononuclear manganese complex with the cis-N2O4 six-coordination sphere. The temperature dependence of magnetic data for 1 revealed a dinuclear spin (S1=S2=5\2) weak antiferromagnetic exchange interaction with J= −0.47 cm−1. Complexes 2–4 play a cryomagnetic behaviour followed the Curie–Weiss law.
    關聯: Polyhedron 17(20), pp.3565-3573
    DOI: 10.1016/S0277-5387(98)00150-8
    顯示於類別:[化學學系暨研究所] 期刊論文

    文件中的檔案:

    檔案 描述 大小格式瀏覽次數
    0KbUnknown191檢視/開啟
    index.html0KbHTML34檢視/開啟

    在機構典藏中所有的資料項目都受到原著作權保護.

    TAIR相關文章

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回饋