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    Title: Synthesis of homopropargyl alcohols via sonochemical barbier-type reaction
    Authors: 李世元;Lee, Adam Shih-yuan;Chu, S. F.;Chang, Y. T.;Wang, S. H.
    Contributors: 淡江大學化學學系
    Date: 2004-02-09
    Issue Date: 2009-12-01
    Publisher: Elsevier
    Abstract: A series of homopropargyl alcohols were synthesized from the reaction mixture of zinc powder, 1,2-diiodoethane, 3-bromo-1-propyne and aldehyde or ketone in anhydrous THF under ultrasound. The homopropargyl alcohols were obtained as the only product in all cases when aldehydes were reacted with 3-bromo-1-propyne under this sonochemical Barbier-type reaction condition. The homopropargyl alcohol was produced as the major product and the low contamination of allenyl alcohol was also obtained when ketone was used as substrate under the reaction condition.
    Relation: Tetrahedron Letters 45(7), pp.1551-1553
    DOI: 10.1016/j.tetlet.2003.12.058
    Appears in Collections:[化學學系暨研究所] 期刊論文

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