Synthesis and Characterization of a New Binuclear Copper(II) Complex with an Oxygen Bridge and a B−N Bonded Ligand

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题名:	Synthesis and Characterization of a New Binuclear Copper(II) Complex with an Oxygen Bridge and a B−N Bonded Ligand
作者:	Shyu, H. L.;魏和祥;Wei, Ho-hsiang;Lee, G. H.;Wang, Yu
贡献者:	淡江大學化學學系
日期:	1996-08-28
上传时间:	2009-12-01
出版者:	American Chemical Society (ACS)
摘要:	The first ferromagnetic (2J = 1.60 cm-1) binuclear copper(II) complex, [Cu(LBPh3)]2, which contains the self-assembly O-bridged and B−N bonded ligand LBPh3 (=N-(salicylidene)-N‘-(1-BPh3)-imidazol-2-ylmethylene)-1,3-propanediamine), has been prepared. The X-ray structure of [Cu(LBPh3]2 reveals that in an unusual formation of B−N bonding the boron atom bonds to the nitrogen atom of the imidazolate moiety of the ligand. The copper(II) atoms are bridged by self-assembly of chelated oxygen atoms.
關聯:	Inorganic chemistry 35(18), pp.5396-5398
DOI:	10.1021/ic960333q
显示于类别:	[化學學系暨研究所] 期刊論文

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