Syntheses, molecular and supramolecular structures, and magnetic properties of a mononuclear MnII and a dicyanamide-bridged one-dimensional CuII compound derived from enolic 4-terpyridone

doi:10.1016/j.poly.2007.12.017

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Title:	Syntheses, molecular and supramolecular structures, and magnetic properties of a mononuclear MnII and a dicyanamide-bridged one-dimensional CuII compound derived from enolic 4-terpyridone
Authors:	魏和祥;Wei, Ho-hsiang;P. Misra, C. Y.;Liao, S. Mohanta
Contributors:	淡江大學化學學系
Keywords:	Dicyanamide;4-Terpyridone;One-dimensional;Coordination polymer;Hydrogen bond;Two-dimensional;Magnetic properties
Date:	2008-03-15
Issue Date:	2009-12-01
Publisher:	Elsevier
Abstract:	Syntheses, molecular and supramolecular structures, and magnetic properties of a mononuclear manganese(II) compound [MnII(LH)2](ClO4)2 (1) and a dicyanamide-bridged one-dimensional copper(II) compound [CuII(LH)(μ1,5-dca)]n(NO3)n (2) derived from enolic 4-terpyridone (LH) have been described. The compounds 1 and 2 crystallize in monoclinic P2(1)/nP2(1)/n and triclinic View the MathML sourceP1¯ space groups, respectively, with the following unit cell parameters – 1: a = 8.8281(4) Å, b = 8.7736(4) Å, c = 39.7838(16) Å, β = 95.719(1)°, and Z = 4; 2: a = 7.5342(3) Å, b = 8.9307(4) Å, c = 15.0189(8) Å, α = 73.0032(15)°, β = 81.3701(16)°, γ = 65.461(2)°, and Z = 2. In 1, the metal center is hexacoordinated by three pyridine nitrogens of each of the two enolic 4-terpyridones. In 2, the metal center is pentacoordinated by three pyridine nitrogens of 4-terpyridone and two nitrogens of two end-to-end (EE; μ1,5-) dicyanamide. The coordination geometries of 1 and 2 are distorted octahedral and distorted square pyramidal, respectively. Eight hydrogen bonds, six of C–H⋯O types and two of O–H⋯O types, link the complex cation [MnII(LH)2]2+ and two perchlorate anions into a three-dimensional network in 1. In the case of 2, seven hydrogen bonds, six of C–H⋯O types and one of O–H⋯O type, link the dicyanamide-bridged one-dimensional chains into a two-dimensional sheet consisting of interlinked one-dimensional double-chains. It may be noted that O–H group of enolic 4-terpyridone participates in hydrogen bonding interactions and in developing extended structures in both 1 and 2. Variable-temperature (2–300 K) magnetic susceptibility measurements of both the compounds have been performed to understand the possibility of spin transition in 1 and exchange interaction in 2. However, the susceptibility data of 1 indicate the existence of high-spin manganese(II) throughout the temperature range. In the case of 2, copper(II) centers are noninteracting which is related to the highly distorted coordination geometry of the metal ion.
Relation:	Polyhedron 27(4), pp.1185-1192
DOI:	10.1016/j.poly.2007.12.017
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

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