Studies of the Coordination Reaction Between Aza-bridged Bis-phenanthroline Macrocycle and Metal Ion

機構典藏 > College of Sciences > Graduate Institute & Department of Chemistry > Journal Article > Item 987654321/25261

Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25261

Title:	Studies of the Coordination Reaction Between Aza-bridged Bis-phenanthroline Macrocycle and Metal Ion
Other Titles:	双氮桥联1,10-菲咯啉大环与金属离子的配位反应研究
Authors:	王文竹;Wang, Wen-Jwu;Chuang, Kuo-Shen;Luo, Chi-Fong;Liu, Hai-Yang;Hu, Xi-Ming;Ying, Xiao;Wu, Ting-Wan
Contributors:	淡江大學化學學系
Keywords:	雙氮橋聯1;10-菲咯啉大環;金屬離子;配位反應;Aza-bridged;bis-phenanthroline macrocycle;Metal ion;Coordination reaction
Date:	2002-03
Issue Date:	2009-12-01
Publisher:	中華人民共和國教育部
Abstract:	Homogeneous solution of poor soluble aza-bridged bis-phenanthroline macrocyclic compound(H2HAPP) was obtained by adding K2CO3 to its trifluoroacetate in CH3OH-CH2Cl2[ V (CH3OH): V (CH2Cl2)= 1:1] solution. Coordination reaction between H2HAPPand metal ion Zn(Ⅱ) in CH3OH CH2Cl2[ V (CH3OH): V (CH2Cl2)=1:1] solvent was studied by UV-Vis spectroscopic method, which indicated 1:1 complexing between H2HAPP and Zn(II) ion occurred easily in such a homogeneous system at room temperature. And the formation of ZnHAPPcomplex was further confirmed by FAB MS and 1H NMR spectra.
Relation:	Chemical Journal of Chinese Universities 23(2), pp.182-184
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

Files in This Item:

File	Description	Size	Format
index.html		0Kb	HTML	82	View/Open
Studies of the Coordination Reaction Between Aza-bridged Bis-phenanthroline Macrocycle and Metal Ion.pdf		862Kb	Adobe PDF	3	View/Open