A novel hexanuclear iron(III) complex containing three-coordination symmetries with two bridging μ-alkoxo groups, two μ3-oxo and four μ-catecholato bridges

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25256

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Title:	A novel hexanuclear iron(III) complex containing three-coordination symmetries with two bridging μ-alkoxo groups, two μ3-oxo and four μ-catecholato bridges
Authors:	魏和祥;Wei, Ho-hsiang;Lu, Jian-wei;Lin, Yi-wen;Takahahsi, Masashi
Contributors:	淡江大學化學學系
Keywords:	Iron(III) clusters;μ-Alkoxo–μ3-oxo–μ-catecholato bridges;Crystal structure;Magnetic properties;Mössbauer spectrum
Date:	2008-04
Issue Date:	2009-12-01
Publisher:	Elsevier
Abstract:	The reaction of stoichiometric amount of FeCl3, Schiff-base ligand, NaBPh4 in CH3CN and 3,5-DTBC in CH3OH under O2 did produce a new μ-oxo-bridged hexanuclear iron(III) cluster [Fe6(L)2(μ3-O)2(μ-3,5-DTBC)4(μ-CH3O)2(Cl)2] (BPh4)2 · 2H2O (1) (L = N,N-diethylenetriamino-bis(imidazolaldiminato) with a spin ground state of S = 5.
Relation:	Inorganic Chemistry Communications 11(4), pp.388-391
DOI:	10.1016/j.inoche.2007.12.010
Appears in Collections:	[化學學系暨研究所] 期刊論文

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