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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25256

    Title: A novel hexanuclear iron(III) complex containing three-coordination symmetries with two bridging μ-alkoxo groups, two μ3-oxo and four μ-catecholato bridges
    Authors: 魏和祥;Wei, Ho-hsiang;Lu, Jian-wei;Lin, Yi-wen;Takahahsi, Masashi
    Contributors: 淡江大學化學學系
    Keywords: Iron(III) clusters;μ-Alkoxo–μ3-oxo–μ-catecholato bridges;Crystal structure;Magnetic properties;Mössbauer spectrum
    Date: 2008-04
    Issue Date: 2009-12-01
    Publisher: Elsevier
    Abstract: The reaction of stoichiometric amount of FeCl3, Schiff-base ligand, NaBPh4 in CH3CN and 3,5-DTBC in CH3OH under O2 did produce a new μ-oxo-bridged hexanuclear iron(III) cluster [Fe6(L)2(μ3-O)2(μ-3,5-DTBC)4(μ-CH3O)2(Cl)2] (BPh4)2 · 2H2O (1) (L = N,N-diethylenetriamino-bis(imidazolaldiminato) with a spin ground state of S = 5.
    Relation: Inorganic Chemistry Communications 11(4), pp.388-391
    DOI: 10.1016/j.inoche.2007.12.010
    Appears in Collections:[化學學系暨研究所] 期刊論文

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