English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 49378/84106 (59%)
造訪人次 : 7381965      線上人數 : 56
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25243

    題名: Structure and magnetic properties of one-dimensional metal complexes constructed from alternating dicyanamide linked through binuclear metal tetra-2-pyridylpyrazine subunits
    作者: Hsu, Guang-Yuan;Chen, Chin-Wang;Cheng, Sung-Chung;Lin, Shin-Huang;魏和祥;Wei, Ho-hsiang;Lee, Chin-Jhin
    貢獻者: 淡江大學化學學系
    關鍵詞: Crystal structure;Dicyanamide;Magnetic properties;Metal complexes;Tetra-2-pyridylpyrazine
    日期: 2005-03-10
    上傳時間: 2009-12-01
    出版者: Kidlington: Pergamon
    摘要: The syntheses, structures and magnetic properties of three 1-D complexes with the formulae [Co2(tppz)(dca)4] (1), [Ni2(tppz)(dca)4]C2H5OH (2) and [Cu2(tppz)(dca)(Cl)2](dca) · H2O (3), where tppz = tetra-2-pyridylpyrazine and dca = dicyanamide, are described. Complexes 1–3 are one-dimensional metal-complexes. In 1 the dinuclear tppz-chelated Co(II) centers are linked by two double μ1,5-dca ligands. Compound 2 forms a ladder-like structure in which the rungs are formed by bis-chelating tppz bridged dinuclear Ni(II) ions and the uprights by μ1,5-dca units. Compound 3 forms a helical chain structure which consists of alternately single μ1,5-dca linked dinuclear tppz-chelated Cu-centers. The temperature dependence of magnetic measurements show antiferromagnetic couplings between two metal ions with a pathway through tppz and μ1,5-dca in all cases, with J = −1.10 cm−1, J′ = −0.05 cm−1 for 1, J = −1.28 cm−1, J′ = −0.11 cm−1 and D = 9.50 cm−1 for 2, and J = −10.26 cm−1, J′ = −0.06 cm−1 for 3.
    關聯: Polyhedron 24(4), pp.487-494
    DOI: 10.1016/j.poly.2004.12.010
    顯示於類別:[化學學系暨研究所] 期刊論文


    檔案 大小格式瀏覽次數



    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回饋