Structure and magnetic properties of a novel chloro-bridged polymeric cadmium(II) complex with pyridyl-substituted nitronyl nitroxide

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Title:	Structure and magnetic properties of a novel chloro-bridged polymeric cadmium(II) complex with pyridyl-substituted nitronyl nitroxide
Authors:	Huanf, C. F.;魏和祥;Wei, Ho-hsiang;Lee, G. H.;Wang, Yu
Contributors:	淡江大學化學學系
Keywords:	Crystal structures;Magnesium complexes;Cadmium complexes;Nitronyl nitroxide complexes;Polymeric complexes
Date:	1998-10-01
Issue Date:	2009-12-01
Publisher:	Elsevier
Abstract:	A complex of 2(2-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxy-3-N-oxide (NIToPy) with Cd(II)Cl2, [(CdCl2)3-(NIToPy)2(C2H5)2], has been structurally and cryomagnetically characterized. The structure is based on a layered zigzagging polymeric chain along the (101) plane; the Cd(II) ions are linked into infinite chains by double chlorine bridges alternating between one CdCl4O2 and two CdCl4NO octahedral coordination units. The temperature-dependence of the magnetic susceptibility reveals the presence of a Heisenberg antiferromagnetic exchange interaction of a two spin Full-size image (<1 K) system, with J = −0.25 cm−1 associated with the intermolecular interaction between the NO groups of two neighboring NIToPy radicals.
Relation:	Inorganica Chimica Acta 279(2), pp.233-237
DOI:	10.1016/S0020-1693(98)00105-4
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

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