淡江大學機構典藏:Item 987654321/25228
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    题名: Stannyl-oriented regioselective allylation and its application to the synthesis of silyl misoprostol
    作者: 李世元;Lee, Adam Shih-Yuan;Wu, C. W.
    贡献者: 淡江大學化學學系
    日期: 1999-10-22
    上传时间: 2009-12-01
    出版者: Elsevier
    摘要: A mixture of Zn, CeCl3, 3-bromo-1-tributylstannylpropene and aldehyde or ketone in THF/PhH (Full-size image (<1 K) was sonicated in a commercial cleaning bath. δ-Tributylstannylhomoallyl alcohol was produced as the sole regioselective product and (E)-stereoisomer was formed as major adduct. Silyl Misoprostol was synthesized by the coupling reaction of cyclopentenone and stannylhomoallyl alcohol.
    關聯: Tetrahedron 55(43), pp.12531-12542
    DOI: 10.1016/S0040-4020(99)00743-7
    显示于类别:[化學學系暨研究所] 期刊論文

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