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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25228

    Title: Stannyl-oriented regioselective allylation and its application to the synthesis of silyl misoprostol
    Authors: 李世元;Lee, Adam Shih-Yuan;Wu, C. W.
    Contributors: 淡江大學化學學系
    Date: 1999-10-22
    Issue Date: 2009-12-01
    Publisher: Elsevier
    Abstract: A mixture of Zn, CeCl3, 3-bromo-1-tributylstannylpropene and aldehyde or ketone in THF/PhH (Full-size image (<1 K) was sonicated in a commercial cleaning bath. δ-Tributylstannylhomoallyl alcohol was produced as the sole regioselective product and (E)-stereoisomer was formed as major adduct. Silyl Misoprostol was synthesized by the coupling reaction of cyclopentenone and stannylhomoallyl alcohol.
    Relation: Tetrahedron 55(43), pp.12531-12542
    DOI: 10.1016/S0040-4020(99)00743-7
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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