Sesquiterpene constituents from the essential oils of the liverworts Mylia taylorii and Mylia nuda

doi:10.1016/j.phytochem.2004.04.039

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25197

Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25197

Title:	Sesquiterpene constituents from the essential oils of the liverworts Mylia taylorii and Mylia nuda
Authors:	吳嘉麗;Wu, Chia-li;von Reuss, Stephan H.;Muhle, Hermann;Koenig, Wilfried A.
Contributors:	淡江大學化學學系
Keywords:	Mylia taylorii;Mylia nuda;Liverworts;Sesquiterpenoids;Structure elucidation
Date:	2004-08-01
Issue Date:	2009-12-01
Publisher:	Elsevier
Abstract:	The essential oils and extracts of Mylia taylorii and M. nuda were investigated by gas chromatography, mass spectrometry, NMR spectroscopy and chemical correlations. Beside several known compounds 13 new constituents including three new carbon skeletons could be identified. Four hydrocarbons with a molecular formula of C15H22 (m/z 202) were identified as myli-4(15)-ene (1), aromadendra-1(10),4(15)-diene (19), aromadendra-4,10(14)-diene (20) and aromadendra-4,9-diene (21). Three oxaspiro-compounds were identified as 7-epi-bourbon-3-en-5,11-oxide (22), guai-3,10(14)-dien-5,11-oxide (23) and guai-3,9-dien-5,11-oxide (24). The absolute configuration of myli-4(15)-en-3-one (5) could be established by chemical correlation. Together with α-taylorione (7) the corresponding 6,11-seco-compound taylopyran (25) with a new carbon skeleton was identified which serves as a precursor to taylocyclane (26) and taylofuran (27). Taynudol (28) contains a new carbon skeleton with a cyclobutenyl structure.
Relation:	Phytochemistry 65(15), pp.2277-2291
DOI:	10.1016/j.phytochem.2004.04.039
Appears in Collections:	[化學學系暨研究所] 期刊論文

Files in This Item:

File	Description	Size	Format
		0Kb	Unknown	385	View/Open
Sesquiterpene constituents from the essential oils of the liverworts Mylia taylorii and Mylia nuda.pdf		404Kb	Adobe PDF	2	View/Open

Loading...