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    题名: Rietveld analysis on Gd(Ba2−xAx)Cu3Oy (A = Ca, Sr) superconductors
    作者: Kao, H.-C. I.;Chin, C. H.;Huang, R. C.;Wang, C. M.
    贡献者: 淡江大學化學學系
    关键词: Calcination;Calcium;Composition;Oxygen;Perovskite;Sintering;Solubility;Strontium;Substitution reactions;Superconducting transition temperature;Superconductivity;X ray diffraction analysis;Conventional solid state reaction;Orthorhombicity;Partial substitution;Rietveld analysis;Oxide superconductors
    日期: 2000-11
    上传时间: 2013-07-09 15:27:48 (UTC+8)
    出版者: Amsterdam: Elsevier BV * North-Holland
    摘要: Two series of single phase triple-perovskite superconducting samples with nominal compositions of Gd(Ba2−xCax)Cu3Oy (Ca series, 0 ≤ x ≤ 0.30) and Gd(Ba2−xSrx)Cu3Oy (Sr series, 0 ≤ x′ ≤ 1.0) were prepared. Orthorhombicity decreases with increasing amount of Ca or Sr substitution. Part of Ca ions occupy R site and push the same amount of Gd3+ ion into Ba site, attracting negative oxygen ions to randomly occupy O(4) and O(5) sites on the basal plane which leads to a further reduction of orthorhombicity in Gd(Ba2−xCax)Cu3Oy series compared with the same amount of substitution in Sr series, in which, Sr only occupies the Ba site. Tc is dependent on the orthorhombicity of these samples, no matter wheater it is Ca or Sr substitution.
    關聯: Physica C: Superconductivity and its Applications 341-348(PART 1), pp.623-624
    DOI: 10.1016/S0921-4534(00)00619-5
    显示于类别:[化學學系暨研究所] 期刊論文


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