A new example of the methyl substitution effect on the spin-state in solid iron-diimine complexes

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Title:	A new example of the methyl substitution effect on the spin-state in solid iron-diimine complexes
Other Titles:	鐵－雙亞胺錯合物的自旋狀態之甲基取代效應的新例
Authors:	魏和祥;邱碧昭;古煥球
Contributors:	淡江大學化學學系
Date:	1987-03
Issue Date:	2009-12-01
Publisher:	中央研究院化學研究所
Abstract:	合成新的鐵（II）-雙亞胺錯合物，組成為FeL_2 (NCS)_2，L代表雙配位座雙亞胺配位子；如N-環戊烷基-2-吡啶醛亞胺，N-環庚烷基-2-吡啶醛亞胺，與其6-甲基取代衍生物。其鐵（II）之基態電子自旋狀態由變溫梅思堡光譜及變溫磁化率測定加以探討。 The iron (II)-diimine complexes of the type [FeL_2(NCS)_2] have been prepared and characterized, where L denotes the bidentate diimine ligands; such as N-cyclopentyl-2-pyridinaldimine and N-cycloheptyl-2-pyridinaldimine and their 6- position methyl-substituted derivatives. The electronic ground spin-state of iron (II) in these complexes has been studied by means of Mossbauer spectroscopy and magnetic susceptibility measurements.
Relation:	中央研究院化學研究所集刊 34，頁87-93
DOI:	10.6522/BICAS.1987.34.12
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

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