English  |  正體中文  |  简体中文  |  Items with full text/Total items : 49287/83828 (59%)
Visitors : 7154845      Online Users : 56
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25145


    Title: A new example of the methyl substitution effect on the spin-state in solid iron-diimine complexes
    Other Titles: 鐵-雙亞胺錯合物的自旋狀態之甲基取代效應的新例
    Authors: 魏和祥;邱碧昭;古煥球
    Contributors: 淡江大學化學學系
    Date: 1987-03-01
    Issue Date: 2009-12-01
    Publisher: 中央研究院化學研究所
    Abstract: 合成新的鐵(II)-雙亞胺錯合物,組成為FeL_2 (NCS)_2,L代表雙配位座雙亞胺配位子;如N-環戊烷基-2-吡啶醛亞胺,N-環庚烷基-2-吡啶醛亞胺,與其6-甲基取代衍生物。其鐵(II)之基態電子自旋狀態由變溫梅思堡光譜及變溫磁化率測定加以探討。
    The iron (II)-diimine complexes of the type [FeL_2(NCS)_2] have been prepared and characterized, where L denotes the bidentate diimine ligands; such as N-cyclopentyl-2-pyridinaldimine and N-cycloheptyl-2-pyridinaldimine and their 6- position methyl-substituted derivatives. The electronic ground spin-state of iron (II) in these complexes has been studied by means of Mossbauer spectroscopy and magnetic susceptibility measurements.
    Relation: 中央研究院化學研究所集刊 34,頁87-93
    DOI: 10.6522/BICAS.1987.34.12
    Appears in Collections:[化學學系暨研究所] 期刊論文

    Files in This Item:

    There are no files associated with this item.

    All items in 機構典藏 are protected by copyright, with all rights reserved.


    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback