Preparation and mossbauer spectroscopic studies of 1', 1'''-diacetyl and 1'-acetyl-1'''-(1-naphthylimino-ethyl)biferrocenes and their partially oxidized biferrocenium salts

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25137

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题名:	Preparation and mossbauer spectroscopic studies of 1', 1'''-diacetyl and 1'-acetyl-1'''-(1-naphthylimino-ethyl)biferrocenes and their partially oxidized biferrocenium salts
作者:	魏和祥;Wei, Ho-hsiang;Hwang, I. S.;Cheng, M. C.;Wang, Yu
贡献者:	淡江大學化學學系
关键词:	Ferrocene;Acetyl;Mössbauer spectroscopy
日期:	1994-05-17
上传时间:	2009-12-01
出版者:	Elsevier
摘要:	The 1′,1‴-diacetyl and 1′-acetyl-1‴-(1-naphthylimino-ethyl)substituted biferrocenes, CH3COFcFcCOCH3 (1) and CH3COFcFcC(CH3)Nnp (2), where Fc = C5H4FeC5H4 and np = 1-naphthyl, and the corresponding monocations as salts with I3−, I5−, FeCl4− and CuI2− have been prepared. The crystal structures of 1 and 2 have been determined. The temperature-dependent Mössbauer spectra of the biferrocenium salts with the exception of the I3− salt from 2 revealed them all to be of the mixed-valence type. The interaction between counter anions and the biferrocenium cations is discussed.
關聯:	Journal of organometallic chemistry 470(1-2), pp.161-167
DOI:	10.1016/0022-328X(94)80161-4
显示于类别:	[化學學系暨研究所] 期刊論文

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