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    題名: Physical properties of trans-stilbene-TCNQ complex
    作者: 高惠春;Kao, Huey-chuen I.;Wang, Su-fen;Chen, Mu-jung
    貢獻者: 淡江大學化學學系
    日期: 1987-03
    上傳時間: 2009-12-01
    出版者: Elsevier
    摘要: The 1:1 trans-stilbene (STB)-TCNQ charge-transfer complex has been isolated and its crystal structure determined. It is stable at 150°C under the N2 atmosphere. Charge-transfer band is found at 612 nm with the molar extinction coefficient of 3.21 × 103 mol−1 dm3cm−1 in CH2Cl2 solution and the association constant is 0.31 mol−1dm3 at 295 K. Electrical conductivity is 4.5 × 10−11 Scm−1 at 300 K along the needle axis. The activation energy is 0.83 eV with semiconducting property. Magnetic susceptibility is 5.2 × 10−5 emu mol−1 which is weakly paramagnetic.
    關聯: Synthetic metals 19(1-3), pp.475-480
    DOI: 10.1016/0379-6779(87)90400-0
    顯示於類別:[化學工程與材料工程學系暨研究所] 期刊論文

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